![]() ![]() Renpenning J, Kümmel S, Hitzfeld KL, Schimmelmann A, Gehre M (2015) Compound-specific hydrogen isotope analysis of heteroatom-bearing compounds via gas chromatography – chromium-based high-temperature conversion (Cr/HTC) – isotope ratio mass spectrometry. Povinec PP, Aoyama M, Biddulph D, Breier R, Buesseler K, Chang CC, Golser R, Hou XL, Ješkovský M, Jull AJT, Kaizer J, Nakano M, Nies H, Palcsu L, Papp L, Pham MK, Steier P, Zhang LY (2013) Cesium, iodine and tritium in NW Pacific waters – a comparison of the Fukushima impact with global fallout. McKeegan KD, Leshin LA (2001) Stable isotope variations in extraterrestrial materials. Martins Z (2011) Organic chemistry of carbonaceous meteorites. In: Gross ML, Caprioli RM (eds) The encyclopedia of mass spectrometry, vol 5. Lis GP, Sauer PE (2010) Variations of abundances of hydrogen isotopes in nature. Kendall C, Coplen TB (2001) Distribution of oxygen-18 and deuterium in river waters across the United States. The Royal Society of Chemistry (RCS) Publishing, Cambridge, 376 pp Jochmann MA, Schmidt TC (2012) Compound-specific stable isotope analysis. ![]() Hayes JM (2001) Fractionation of carbon and hydrogen isotopes in biosynthetic processes. ![]() Įtiope G, Sherwood Lollar B (2013) Abiotic methane on earth. Įlsner M, Jochmann MA, Hofstetter TB, Hunkeler D, Bernstein A, Schmidt TC, Schimmelmann A (2012) Current challenges in compound-specific stable isotope analysis of environmental organic contaminants. Įhleringer JR, Chesson LA, Valenzuela LO, Tipple BJ, Martinelli LA (2015) Stable isotopes trace the truth: from adulterated foods to crime scenes. ![]() Ĭoplen TB (2011) Guidelines and recommended terms for expression of stable-isotope-ratio and gas-ratio measurement results. Ĭlauer N, Chaudhuri S (1995) Clays in crustal environments. īrand WA, Coplen TB, Vogl J, Rosner M, Prohaska T (2014) Assessment of international reference materials for isotope-ratio analysis (IUPAC technical report). īrand WA, Coplen TB (2012) Stable isotope deltas: tiny, yet robust signatures in nature. Elsevier, Amsterdam/Boston, pp 739–822īowen GJ, Kennedy CD, Liu Z, Stalker J (2011) Water balance model for mean annual hydrogen and oxygen isotope distributions in surface waters of the contiguous United States. īeauchemin D, Matthews DE (2010) Chapter 10: isotope ratio mass spectrometry (IRMS): light elements (C, H, O, N, S). Īltwegg K, Balsiger H, Bar-Nun A, Berthelier JJ, Bieler A, Bochsler P, Briois C, Calmonte U, Combi M, De Keyser J, Eberhardt P, Fiethe B, Fuselier S, Gasc S, Gombosi TI, Hansen KC, Hässig M, Jäckel A, Kopp E, Korth A, LeRoy L, Mall U, Marty B, Mousis O, Neefs E, Owen T, Rème H, Rubin M, Sémon T, Tzou CY, Waite H, Wurz P (2015) 67P/Churyumov-Gerasimenko, a Jupiter family comet with a high D/H ratio. To confirm your answer, compare the calculated value to the weighted mass displayed on the periodic table.Affolter S, Fleitmann D, Leuenberger M (2014) New online method for water isotope analysis of speleothem inclusions using laser absorption spectroscopy (WS-CRDS). The atomic mass of oxygen (use percent natural abundance data from Table 2.5.1) would be calculated as follows:Ītomic mass = (%1)(mass 1) (%2)(mass 2) (%3)(mass 3) For chlorine, there are only two naturally occurring isotopes so there are only two terms.Ītomic mass = (%1)(mass 1) (%2)(mass 2) ⋯Īnother example: oxygen exists as a mixture that is 99.759% 16O, 0.037% 17O and 0.204% 18O. This is repeated until there is a term for each isotope. The weighted average is determined by multiplying the percent of natural abundance by the actual mass of the isotope. The atomic mass of an element is the weighted average of the atomic masses of the naturally occurring isotopes of that element. Why? The reason is that we need to take into account the natural abundance percentages of each isotope in order to calculate what is called the weighted average. = 35.968 \,u \nonumber \]Īs you can see, the average atomic mass given in the last column of the table above (35.453) is significantly lower. ![]()
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![]() ![]() Launchd: ~/Library/LaunchAgents/Įxecutable: /Applications/Amazon Music.app/Contents/MacOS/Amazon Music Helper Launchd: ~/Library/LaunchAgents/Įxecutable: /Users/***/Library/Application Support/DxO Labs/LaunchAgents/opticsPro11LaunchAgentĭetails: Exact match found in the whitelist - probably OK Gatekeeper Mac App Store and identified developers Interface usbserial-A104VKK6: FT232R USB UART Interface usbmodem143131: TAMRON TAP-in Console System modifications - There are a large number of system modifications running in the background.ģ2-bit Apps - This machine has 32-bits apps that may have problems in the future.ġ 3.2 GHz Intel Core i5 (i5-6500) CPU: 4-coreĭisk0 - APPLE SSD AP0032H 24.00 GB (Solid State - TRIM: Yes) They appear to be legitimate but should be reviewed. Unsigned files - There is unsigned software installed. Heavy RAM usage - This machine is using a large amount of RAM.Īpps crashing - There have been numerous app crashes.Īpps with heavy CPU usage - There have been numerous cases of apps with heavy CPU usage.Ĭlean up - There are orphan files that could be removed. These issues do not need immediate attention but they may indicate future problems. I would be most grateful.ĭominic I hope this is better, yes, I am a bit thick? I have searched for a direct download from Apple-to no avail. Where my keyboard was once ABC, I added US-all to no avail. I have tried while dictation is enabled, disabled. I have tried while Siri is enabled, disabled. Changed the region from Indonesia to United States. I have, while maintaining English (US) as the priority language, added other languages, removed other languages. Looking at activity monitor, this process, "Speech Downloader," itself sends and receives 0 packets of data. With the -15 priority, the process continues on until no end. I tried assigning a -10 priority to the 976 pid and also a -15 priority. The problem is consistent, before and after update. On this same day, I downloaded the 12.2.1 update, from 12.2. Monterey 12.2.1 Mac Mini Late 2014: An unexpected error occurred while downloading the Voice Control language "English (United States)" This "unexpected error" has occurred more than 20 times during the better part of day. ![]() ![]()
![]() ![]() With its beautiful music and simple yet challenging gameplay, Piano Tiles is sure to keep you entertained for hours on end. The game has gained a huge following and has become a popular choice for mobile gaming. 's Piano Tiles is a game that is easy to learn but hard to master, making it an addictive and engaging experience for players of all ages. Piano Tiles is known for its simple yet elegant graphics, with a black and white color scheme that allows the player to focus solely on the tiles. The game features a wide selection of music to choose from, including classical, pop, and rock songs. Īs you tap the tiles, you create beautiful music, with each tile producing a unique note. Susanna L030 - Prelude in C Major No. There are various game modes to choose from, including Classic mode, Arcade mode, and Zen mode, each with their own unique challenges. The gameplay is simple yet challenging, with the tiles moving faster and faster as you progress through the levels. The objective of this online game is to tap the black tiles as they scroll down the screen while avoiding the white tiles. When playing music under a particular scale, you should normally avoid any key without a blue dot, although composers sometimes use altered notes which are not within the scale.□ Piano Tiles is a fast-paced, addictive music game that challenges your hand-eye coordination and reflexes. The tonal center or tonic is the note where the scale hierarchy starts and it is represented on the virtual piano with a darker blue dot. E minor and A minor both use the same minor scale). You can also use scales to create your own melodies and set the mood of your piece.Īny chosen scale can be transported to any tonal center (e.g. Practicing scales will provide you with the necessary skills to play different styles of music like Jazz, Flamenco or Blues. Musical scales are an essential part of music improvisation and composition. However, the distance between C and D, for example, is a full tone (or two semitones). For example, the distance between C and C# (black key next to C), or the distance between E and F (both being white keys). In other words, a semitone is also the distance between two consecutive keys on the piano. A semitone is the minimum distance between two consecutive notes in any tempered scale (12 equal semitones per octave). Ī scale is a set of musical notes ordered as a well-defined sequence of intervals (tones and semitones). Hampton Hawes, piano Jim Hall, guitar Red Mitchell, bass Bruz Freeman, drums.: same personnel. You just need to press the MIDI button under the piano to select your MIDI device. C3546 All Night Session With The Hampton Hawes Quartet 2 1958. ![]() But don’t tap on the white ones if you do, you’ll have to start again from the beginning. The objective of the game is simple: tap on the black tiles as they zip by. IMPORT-Export opportunity, profitable world-wide, mail-order business from home. ApPeter Piano Tiles is a mobile game that has taken the world by storm. World’s Fastest Pianist: Most piano key hits in one minute. 2.500 UNUSUAL Hobby, Party Records, Others Free Catalogue. Play the virtual piano using a external MIDI controller. Note: Flag icon represents the native country of the record breaker, not the location where the record was broken.
![]() This is because the issue has already been decided, and the same parties are involved. Res judicata can also be used as an affirmative defense to bar the same parties from litigating a second lawsuit on the same claim or any other claim arising from the same transaction or series of transactions that could have been raised in the first suit.įor res judicata to apply, three essential elements must be present: (1) an earlier decision on the issue, (2) a final judgment on the merits, and (3) the involvement of the same parties or parties in privity with the original parties.įor example, if a person sues a company for breach of contract and loses, they cannot sue the same company again for the same breach of contract. The virtual-representation doctrine is related to the concept of res judicata, which is an issue that has been definitively settled by judicial decision. This is because the husband's interests were closely aligned with the wife's interests, and he adequately represented her in court. ![]() ![]() The virtual- representation doctrine is a legal principle that allows a judgment to bind a person who is not a party to the litigation if one of the parties is so closely aligned with the nonparty's interests that the nonparty has been adequately represented by the party in court.įor example, if a husband is sued and his wife has a similar interest in the case, the judgment may also bind the wife even if she was not named as a party. ![]() ![]() It creates unique content, so you don’t even have to worry about plagiarism! We’ve created IQ Hashtags Caption Generator to produce the most original, plagiarism-free captions that are just as human-readable as every caption you write on your own. Now, instead of focusing on finding the right words, you can turn your simple ideas into meaningful captions in a matter of seconds. In addition, it will increase your overall content output without spending long hours researching and crafting captions – ultimately saving you so much time and effort. ![]() It took a while, but we know it was worth it, because THIS IS IT! Our AI-Powered Caption Generator will help you, creators and entrepreneurs, produce quality writing much quicker and more efficiently than before. Our new feature uses the most advanced artificial intelligence to assist with writing use cases and is built on large language models. There are plenty of advantages to AI applications, and it has the potential to revolutionize any sector. It really is an AI-powered feature that works like magic.ĪI (Artificial Intelligence) has been creating quite a big buzz. Our innovative tool allows you to create unique captions almost without writing a single word yourself – it’s all done by our AI writing assistant. Unfortunately, creative block is real and can significantly affect your posting schedule.ĪI-powered captions with a few clicks – speed up content creation!įind the right words for any post by generating unique captions with a couple of clicks. Sometimes many, many times a week! The pressure of comparing yourself to other creators, deadlines, and perfectionism can cause this sudden intellectual affliction. The fact is that almost every Instagram creator faces a creative block at some point. You find yourself staring at your mobile screen or the blank page, struggling to find the right words to finish the sentence. A creative block is a common phenomenon most accurately described as a frustrating feeling of being stuck in the creative writing process without the ability to move forward and create anything new. Your captions have turned to mush, you don’t have any creative bone left in your body, and you’d like to throw in the towel. ![]() We know it happens to every content creator. As you already know, our mission at IQ Hashtags is to help social media managers, business owners, content creators, marketers, and entrepreneurs of all kinds save time, energy, and money – and here we are, proving it again!īlank-page syndrome. We’re sure it will help you say goodbye to every creative block and take your content to the next level. You choose! Using our cutting-edge AI models, it generates Instagram captions in creative-writing quality within seconds. It’s an AI-powered writing tool that makes it easy for you to write creative captions for your Instagram posts – static posts, carousels, or Reels. It’s time to overcome the blank-page syndrome! We’re thrilled to announce our newest feature called AI Instagram Caption Generator, unlocking the magic of AI for everybody using our IQ Hashtags Tool. ![]() ![]() ![]() It will keep them happy for hours.Įaster lily is a biblical flower associated with the resurrection of the Christ. Your kids will love coloring this long eared and short-tailed creature. The bunny also evaluates whether the children were well behaved or disobedient at the start of the Easter season. It is believed that Easter bunnies deliver decorated eggs to children who leave their baskets on Easter Sunday night. Rabbits are known to be prolific procreators, symbolizing the new life and fertility of Easter. The Easter bunny is a prominent symbol of Easter. You can also print out the page and stick up on the display. Here is a pretty Easter egg picture for your kids to color. Easter egg symbolizes the empty tomb of Jesus. Now chocolate eggs or plastic eggs filled with candies and other sweet treats are gifted. Earlier, bird’s eggs painted in bright colors were given as a gift. The tradition of celebrating Easter with eggs dates back to the 13th century. You can also print out the page and use it to wrap small gifts. Make your kids color this beautiful page to help them discover the essence of this springtime festival. According to the legend, a white hare would gift Easter baskets filled with brightly colored eggs, candies and other goodies for the kids to gorge on. It is not just an ensemble of goodies and treats it signifies a new life, rebirth and renewal. ![]() It has played a pivotal role in the celebrations of Easter for ages. Easter Basket:Įaster basket is a hallmark of this festival. This will be the ideal way of developing coloring skills in your younger child & also offers hours of fun. ![]() ![]() Here is a beautiful collection of free Easter coloring pages to print out and color. Top 25 Colorful Easter Coloring Pages For Kids Here are 25 Easter coloring sheets to help your kids acquire knowledge about this springtime festival in a fun way. The mere word “Easter” evokes the memories of lilies, baskets, gifts, bunnies and chocolate, eggs and much more. The festival is therefore celebrated as a symbolic victory over death. It is the day when Jesus came back to life after being crucified.
![]() Overall, it just did not seem practical to convert a ukulele. It seems marginally possible with specific nylon strings. Some knowledgeable people discussed this on Music.StackExchange. See screenshot below. Tuning nylon strings on a ukulele to the cavaquinho scale apparently exerts dangerous tension as well.Even if you stick with nylon, tuning becomes an issue – see the next point. Nylon strings sound completely different than steel.The general online consensus is that stringing a ukulele with steel will deform or damage it. Steel strings have a much higher amount of tension than nylon when tuned to the same note.These don’t seem significant, but they are. Ukuleles are strung with nylon strings.Ukeleles are tuned gCEA (the first string is a high “g”). The most common tuning for cavaquinhos in Brazilian music is DGBD (from low to high).This is very similar to a soprano-sized ukulele. The scale length of a cavaquinho is around 350 mm (13-14 in).Here are some of the similarities and differences: They’re widely available at local and online retailers. My second thought was to simply buy a ukulele and re-string/re-tune it to match a cavaquinho. Ask if they have experience working on mandolins and check reviews online to get a better idea. I’m not sure if your local Guitar Center would be able to perform a setup on a cavaquinho. ![]() Even though they had not heard of a cavaquinho, I felt confident that they had the skills to fix it. Electric guitars are easy to learn on, as the bridge is easily adjustable, but for an acoustic style instrument, I felt more comfortable paying someone who has years of experience.Ī word about guitar shops – my local guitar shop is a small store that has been in business forever, and has very knowledgeable staff. You can setup your instrument yourself, but it is somewhat of an art – how much to adjust, getting the action low without buzzing, and allowing the wood to acclimate. ![]() Unless you’re buying your instrument from a physical shop, I would definitely include the cost of a setup in your budget. I don’t know how cavaquinhos ship in Brazil, but it seems guitars in the US come with a high action, and it’s up to the player to adjust it down. His advice was that a cheaper instrument could’ve had much worse problems – uneven frets, bowed neck, that would be more difficult to repair. I talked to the guitar technician about how I was a little annoyed that an expensive instrument still needed work done, as I might as well get a cheaper one. Now, they require much less effort to press, and the intonation problems are gone. They also changed the strings – I had purchased a set online, so that was no added cost.īefore, I had to press relatively hard to cleanly fret notes, and found myself gritting my teeth at times. I brought my cavaquinho to my local guitar shop for setup – they charged me $60, which included fret polishing, fretboard oiling, and sanding the underside of the bridge to bring the strings down to the proper height. “Action” refers to how the instrument physically plays, and in particular the height of the strings above the fretboard. ![]() This is often caused by action that is too high. In my case, an open string would be in tune, but the octave up (12th fret) was very noticeably sharp. For those unfamiliar with fretted string instruments, intonation refers to the accuracy of the pitch, particularly when the higher frets are played. My instrument had some very bad intonation problems. Although mine was a “factory demo,” I believe this issue may be pretty universal. I originally thought that a pricey instrument would come ready to play out of the box – I was apparently mistaken. I remember seeing Adam Savage, of Mythbusters, talking at a live show about his realization that the ability to become mediocre at many skills is, in itself, a valuable skill.įor those of you just stumbling on my site, thank you for visiting! I hope the few posts I’ve made over the years are helpful, and wish you the best of luck in your Cavaquinho endeavors. I don’t believe it’s negative trait to try new things, even if it doesn’t lead to a lifelong commitment. I’ve picked up and dropped many hobbies, activities, instruments, and projects in life – such is my nature, and that of many other “jack of all trades” types. I feel pretty good about it, given that most of the things we tend to buy in life depreciate horribly. It probably could’ve sold for more, but I felt it was a fair price. I sold it for $350, which is only $60 less than I purchased it for 4 years ago. I initially made a posting on Craigslist, but was contacted by someone out of state to purchase, so I threw it up on Ebay to facilitate the transaction. It’s been a long time coming, but I just hadn’t been practicing or playing enough to justify keeping my instrument around. ![]() ![]() ![]() We wanted it to be like a nightclub, and to have Bo be our version of Norm from ‘Cheers.’ Everybody knows her name, she’s at home there, and Woody is the fish out of water.” “We scaled up the pinball machine a ton, because what you see would never actually fit inside the machine. “In live-action films you can cheat the exterior and have a different set for the interior, and we did the same thing in the computer. “One of the challenges was, ‘How many characters can we get into this pinball machine?'” he said. Of course, the real pinball machine wouldn’t be quite big enough for all those toys, so Cooley and his crew fudged things. “I was able to do toys from all different eras: old iron toys, tin soldiers, plastic windup toys … To me, that makes the ‘Toy Story’ world feel bigger.”Īlso Read: 'Toy Story 4' Film Review: Woody and Company Return for a Sequel That's No Buzz-Kill “The detail you can achieve now is insane,” Cooley said. At one point, Woody and Bo venture into the store on a rescue mission, and she leads him into a pinball machine that turns out to be a nightclub for toys on the inside. Many of the key sequences in the film take place in a cluttered antique store secretly ruled by a sinister doll (Christina Hendricks) and her evil henchmen. It felt like having another whole brain working on Bo.” “It helped me pull back to focus on the big picture. “And in this case, there were key people in each one of those departments that pulled themselves together and called themselves Team Bo, who said, ‘We’re gonna make this character the best she can be, and not fall into tropes or stereotypes. “We have so many different departments at work on a single character,” he said. The character of Bo Peep, he added, had a special team of female Pixar employees looking out for her. We tried to make how she comes back into the picture really interesting, so she became the very thing Woody was always afraid of: She’s a lost toy, and she’s loving it.”Īlso Read: 'Toy Story 2' Blooper Scene About Sexual Misconduct Edited Out of Re-Release (Video)ĪNATOMY OF A SCENE: (1) Initial storyboard by Aphton Corbin (2) concept art by John Lee (3) sets drawn during computer modeling and shading (4) layout using a virtual camera (5) animation done by Pixar Animation Department (6) lighting to place virtual light sources within the image (7) effects and final image (Pixar) We had versions where she was more of a villain, not completely on the up-and-up. “Her return was always a part of it - but how she returned and what she was like when she returned was always changing. ![]() “The code name for this movie internally was ‘Peep,'” he said. With this one, early on it was, ‘We know these characters, we know the world, let’s just play around and see what happens.’ But that was the tough part - we’ve been with Woody for three films, what’s next for him?”īut even as the story changed through Pixar’s exacting development process, Cooley said one constant was the character of Bo Peep (voiced by Annie Potts), who would come back into the life of Woody (Tom Hanks) as more than just a love interest. “I think you can either approach a story from the fun of the world and the characters, or the protagonist’s point of view and their character arc. “We had a lot of different physical location and character ideas,” he said. The story, he said, changed dramatically throughout the development process. “These characters are so important to people, and to me, that I wanted to make sure this didn’t feel like we were tacking something onto the ‘Toy Story’ world,” said Cooley, who began the project as co-director to Pixar chief John Lasseter and ended up as the sole director when Lasseter left the project (and shortly thereafter, the company) amid accusations of misconduct.Īlso Read: Golden Globes: 'Toy Story 4' Helped Josh Cooley Focus During Pixar's Tough Transition Instead, he said, it was an existential question: “What is the reason this movie exists?” This story about “Toy Story 4” first appeared in the Oscar Nominations Preview issue of TheWrap’s Oscar magazine.įor director Josh Cooley, the first question to answer before he got to work on “Toy Story 4” wasn’t, “What should happen to Woody and Buzz?” or “How much time should have elapsed since the events of ‘Toy Story 3’?” ![]() ![]() To produce a screenshot (of course only with material with which you are making no copyright infringement), there are two roundabout ways of doing this: This is the case even if you have no desire to record any part of the movie in your screenshot or you have even gone to the effort of getting the rights to the movie. For copyright reasons, Apple has made it impossible to make screengrabs while the playback software is running. For example, Apple has configured it so that it is not possible to make a screenshot of a movie that is being played via the DVD player software. This usually has something to do with the program that you are attempting to display. It can sometimes be the case that making a screen capture on a Mac doesn’t work. (It is also possible to install a button in the Touch Bar specifically for the creation of MacBook screenshots.) The shortcut key for this form of screen grab – as the Touch Bar is located underneath the actual monitor – is + +. A requirement for this is that you have the update macOS Sierra 10.12.1 or later. It is also possible to make a screenshot of this display. Touch Bar: As of 2016, MacBook Pros are fitted out with an additional navigation bar – an OLED touch screen known as the Touch Bar.Like with the other processes, you can cancel this process by pressing the Esc button. Now when you click into a menu, the title will also be a part of the screenshot. This can only be done if, prior to clicking your mouse, you transform the pointer into a crosshair cursor by pressing the spacebar. However, this will not save the title of the menu. Using the cursor, click on the menu and create your screenshot. To do this simply open the menu and press + +. Menu: Even a menu can be saved separately as a screenshot on a Mac.This process can also be cancelled at any time by pressing the Esc button. Simply click on the window that you wish to make a screenshot of. Now by pressing the space bar the cursor will become a camera symbol. Once again, your mouse will transform into a crosshair cursor. Window: If it is the case that you wish to save an entire window (and nothing else) as a screenshot, then you should also be pressing the button combination of + +.If you wish to cancel the screengrab during the process, simply press the Esc button. The screenshot will then be performed at this moment. Move the cursor to where you would like to begin the screen grab, then click and pull to the desired size before releasing the mouse again. ![]() In this case, the mouse pointer will turn into a crosshair cursor. Rectangular area: Press + + to grab a rectangular section of a screen.Entire screen: You can make a screenshot of the entire display by pressing + +.There are different buttons depending on which area of a macOS or OS X you wish to make a screen grab of: Apple users will always need to press a combination of buttons (a shortcut) to make a screenshot on a Mac. It is this button that allows Windows users, with one single press of a button, to make a screen grab of everything on display on a monitor. Apple devices don’t have a ‘Print Screen’ button. ![]() |
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